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3. Braniac (James Marsters)
There’s a pattern forming here – allies of Clark, gone bad, tend to make for the best Smallville villains. Braniac, after arriving in season five, poses as Clark’s teacher Milton Fine before going mental and causing all kinds of havoc. We’re fans of James Marsters and in Smallville he gave viewers a villain they could really invest in.
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i think Zod should be in the top 5 i though he was a really awesome villian
Great list and Lex deserves the top spot! Who thought Lana looked especially hot in Chuck recently? :) Hope season ten of Smallville rocks!